gel battery is a developmental classification of lead-acid battery by adding gelling agent to sulfuric acid to make the sulfuric acid electrolyte into a colloidal state. A battery with a gelled electrolyte is usually called a gel battery.
The difference between gel battery and conventional lead-acid battery is further developed from the initial understanding of electrolyte gelling to the research of electrochemical characteristics of electrolyte basic structure and the promotion of application in the plate grid and active substance.
Its most important characteristics are: with smaller industrial cost, it can produce higher quality gel battery with flat discharge curve and high inflection point, and its energy and power are more than 20% larger than conventional lead-acid batteries.
And its life is generally about twice as long as conventional lead-acid batteries, and its high temperature and low temperature characteristics are much better.
gel battery features
Compared with lithium ion battery electrolyte, the electrolyte of gel battery is gel-like, no flow, no acid stratification, safe and reliable.
The main component of electrolyte is fumed silica (SIO2) substance with particle size close to nanometer, and the surface modification and interface catalysis of fumed silica is realized by using electrochemical surface catalysis, surface modification theory and electrochemical kinetics basic method.
The electrolyte filling volume of the gel battery adopts the liquid-rich type, and the electrolyte can fill the space in the battery tank. gel battery has high thermal capacity and good heat dissipation, and it is not easy to dry out and produce thermal runaway phenomenon under high temperature and overcharging condition.
Good performance of high current discharge, high hydrogen precipitation potential, high recovery ability of deep cycle, long service life. Wide application environment, no thermal runaway and non-discharge of the battery when used in -30-50 degrees Celsius environment.
Floating charge design life: 2V gel battery ≥ 15 years, 12V gel battery ≥ 10 years. Self-discharge is small, generally only a quarter of the AGM battery, storage time can be up to 2 years at room temperature.
Features of main material of gel battery
gel battery silicon powder: produced in the United States Degussa AG200, Cabot, Germany Wacker and other brands of SiO2, characteristics: high purity, high specific surface area (200m2/g), high thickening thixotropy, viscosity stability.
1. gel battery and AGM battery, in addition to the use of electrolyte state is not the same, and the use of the separator is also different from the AGM battery. gel battery uses PVC and PE separators.
2. PVC and PE bulkheads are electronic insulators, while their high porosity makes the bulkheads ionically conductive.
3. Resistance is an important performance of PVC and PE partition, which is determined by the thickness, porosity and curvature of PVC and PE partition, and has an important influence on the high rate of discharge and end voltage level of gel battery.
4. PVC, PE spacer is stable in sulfuric acid, PVC, PE spacer has good mechanical strength, acid corrosion resistance, oxidation resistance, does not precipitate substances harmful to the plate, its stability directly affects the life of the gel battery.
5. The elasticity of PVC and PE spacer can delay the shedding of the active material of the pole plate.
Internal structure of gel battery
Broadly speaking, the difference between gel battery and conventional lead-acid batteries does not only lie in the change of electrohydraulic liquid to colloidal form.
For example, aqueous colloids in the non-solidified state are the same as gel battery in terms of electrochemical classification structure and characteristics. Another example is the attachment of polymer materials in the plate grid, commonly known as ceramic plate grid, which can also be regarded as the application characteristics of gel battery.
Some laboratories have added a target coupling agent in the formulation of the electrode plate, which greatly improves the reaction utilization rate of the active material of the electrode plate, and according to non-public information, it can reach 70wh/kg of weight specific energy level, which are examples of industrial practice and pending industrialization of colloidal battery applications.
Aqueous colloid is a non-disciplinary normative term, a name to distinguish a solidified colloid.
The understanding of colloids is very different between academic classification and customary understanding. The custom mostly considers substances in the physical state of gelled state at room temperature to be called colloids, while in the chemical structure classification, it is defined as substances with the basic structure of the dispersed phase in the range of 1 to 100 nm.
It is the colloidal particle size and its surfactant that determine the electrochemical properties.gel battery has sunk and floated several times in the history, which is related to the battery materials development and technological maturity of colloids.
In the last three or two years, although nanoscale sols have been developed and there is more production practice on the electrochemical application of surfactants, it is difficult for manufacturers to select a suitable gel state colloid in a short period of time.
Aqueous gels are designed as an intermediate product in the development of an acid battery to a colloidal battery, characterized by the elimination of the physical gelling skeleton, retention of functional polymeric group characteristics and surfactants, pure liquid form, used as a sulfuric acid additive, and suitable for making all lead batteries.
Advantages: it does not produce the industrial problems common to colloidal batteries, the manufacturing process is exactly the same as that of acid batteries, the capacity is increased by 5-15% after use, the battery life is extended by 50-100%, the resistance to sulfation of the pole plate is strong, and the corrosion force on the plate grid is much smaller after sulfuric acid modification. The price is also cheaper than conventional colloid.
After using water-based colloid additives, there is no need to add sodium sulfate and phosphoric acid to sulfuric acid. Standard additive amount: 8% by volume.
Comparison of the characteristics of gel battery and AGM lead-acid battery
Environmental protection
gel battery
AGM lead-acid battery
1
Colloidal electrolytes
Ordinary dilute sulfuric acid electrolyte
2
No leakage, environmental protection, safety
/
3
Good water retention and maintenance-free
/
Low temperature performance
gel battery
AGM lead-acid battery
Recipe
Special additives that are co-soluble with colloids
General additives
Performance
-30~45℃ normal operation
-15~45℃ normal work
-10℃ charge and discharge, 73% Ce charge at room temperature, -10℃ discharge, 81% Ce
-10℃ charge and discharge, 65% Ce room temperature charge, -10℃ discharge, 70% Ce
Don’t wait for the power of the gel battery to run out before charging, you should charge it in time after discharging. Try to use a good quality charger for the gel battery, which will help to improve the service life of the gel battery.
The gel battery should be fully charged and stored in a cool and dry place, not near the heat source and not in direct sunlight. Stored for more than a month before use should be recharged, stored for more than three months should do a deep charge put.
When charging in hot weather, pay attention to the gel battery temperature is not too high, do not charge the gel battery drum, such as hand touch too hot, you can stop a pause and then charge. Winter temperature is low, gel battery is easy to undercharge, you can properly extend the charging time (such as 10%).
If it is a group of gel battery, when a single gel battery is found to have problems should be replaced in a timely manner, can extend the life of the whole group of gel battery. Thank you for watching, I believe you will be interested in sodium ion battery.
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Types of Batteries – gel battery
What is a gel battery?
gel battery is a developmental classification of lead-acid battery by adding gelling agent to sulfuric acid to make the sulfuric acid electrolyte into a colloidal state. A battery with a gelled electrolyte is usually called a gel battery.
The difference between gel battery and conventional lead-acid battery is further developed from the initial understanding of electrolyte gelling to the research of electrochemical characteristics of electrolyte basic structure and the promotion of application in the plate grid and active substance.
Its most important characteristics are: with smaller industrial cost, it can produce higher quality gel battery with flat discharge curve and high inflection point, and its energy and power are more than 20% larger than conventional lead-acid batteries.
And its life is generally about twice as long as conventional lead-acid batteries, and its high temperature and low temperature characteristics are much better.
gel battery features
Compared with lithium ion battery electrolyte, the electrolyte of gel battery is gel-like, no flow, no acid stratification, safe and reliable.
The main component of electrolyte is fumed silica (SIO2) substance with particle size close to nanometer, and the surface modification and interface catalysis of fumed silica is realized by using electrochemical surface catalysis, surface modification theory and electrochemical kinetics basic method.
The electrolyte filling volume of the gel battery adopts the liquid-rich type, and the electrolyte can fill the space in the battery tank. gel battery has high thermal capacity and good heat dissipation, and it is not easy to dry out and produce thermal runaway phenomenon under high temperature and overcharging condition.
Good performance of high current discharge, high hydrogen precipitation potential, high recovery ability of deep cycle, long service life. Wide application environment, no thermal runaway and non-discharge of the battery when used in -30-50 degrees Celsius environment.
Floating charge design life: 2V gel battery ≥ 15 years, 12V gel battery ≥ 10 years. Self-discharge is small, generally only a quarter of the AGM battery, storage time can be up to 2 years at room temperature.
Features of main material of gel battery
gel battery silicon powder: produced in the United States Degussa AG200, Cabot, Germany Wacker and other brands of SiO2, characteristics: high purity, high specific surface area (200m2/g), high thickening thixotropy, viscosity stability.
Separator: PVC, PE, PR, PP, etc. lithium battery separator
1. gel battery and AGM battery, in addition to the use of electrolyte state is not the same, and the use of the separator is also different from the AGM battery. gel battery uses PVC and PE separators.
2. PVC and PE bulkheads are electronic insulators, while their high porosity makes the bulkheads ionically conductive.
3. Resistance is an important performance of PVC and PE partition, which is determined by the thickness, porosity and curvature of PVC and PE partition, and has an important influence on the high rate of discharge and end voltage level of gel battery.
4. PVC, PE spacer is stable in sulfuric acid, PVC, PE spacer has good mechanical strength, acid corrosion resistance, oxidation resistance, does not precipitate substances harmful to the plate, its stability directly affects the life of the gel battery.
5. The elasticity of PVC and PE spacer can delay the shedding of the active material of the pole plate.
Internal structure of gel battery
Broadly speaking, the difference between gel battery and conventional lead-acid batteries does not only lie in the change of electrohydraulic liquid to colloidal form.
For example, aqueous colloids in the non-solidified state are the same as gel battery in terms of electrochemical classification structure and characteristics. Another example is the attachment of polymer materials in the plate grid, commonly known as ceramic plate grid, which can also be regarded as the application characteristics of gel battery.
Some laboratories have added a target coupling agent in the formulation of the electrode plate, which greatly improves the reaction utilization rate of the active material of the electrode plate, and according to non-public information, it can reach 70wh/kg of weight specific energy level, which are examples of industrial practice and pending industrialization of colloidal battery applications.
Aqueous colloid is a non-disciplinary normative term, a name to distinguish a solidified colloid.
The understanding of colloids is very different between academic classification and customary understanding. The custom mostly considers substances in the physical state of gelled state at room temperature to be called colloids, while in the chemical structure classification, it is defined as substances with the basic structure of the dispersed phase in the range of 1 to 100 nm.
It is the colloidal particle size and its surfactant that determine the electrochemical properties.gel battery has sunk and floated several times in the history, which is related to the battery materials development and technological maturity of colloids.
In the last three or two years, although nanoscale sols have been developed and there is more production practice on the electrochemical application of surfactants, it is difficult for manufacturers to select a suitable gel state colloid in a short period of time.
Aqueous gels are designed as an intermediate product in the development of an acid battery to a colloidal battery, characterized by the elimination of the physical gelling skeleton, retention of functional polymeric group characteristics and surfactants, pure liquid form, used as a sulfuric acid additive, and suitable for making all lead batteries.
Advantages: it does not produce the industrial problems common to colloidal batteries, the manufacturing process is exactly the same as that of acid batteries, the capacity is increased by 5-15% after use, the battery life is extended by 50-100%, the resistance to sulfation of the pole plate is strong, and the corrosion force on the plate grid is much smaller after sulfuric acid modification. The price is also cheaper than conventional colloid.
After using water-based colloid additives, there is no need to add sodium sulfate and phosphoric acid to sulfuric acid. Standard additive amount: 8% by volume.
Comparison of the characteristics of gel battery and AGM lead-acid battery
Environmental protection
Low temperature performance
The above comparison can also be applied to the choice between gel motorcycle battery and lead acid motorcycle battery.
Correct charging method for gel battery
Don’t wait for the power of the gel battery to run out before charging, you should charge it in time after discharging. Try to use a good quality charger for the gel battery, which will help to improve the service life of the gel battery.
The gel battery should be fully charged and stored in a cool and dry place, not near the heat source and not in direct sunlight. Stored for more than a month before use should be recharged, stored for more than three months should do a deep charge put.
When charging in hot weather, pay attention to the gel battery temperature is not too high, do not charge the gel battery drum, such as hand touch too hot, you can stop a pause and then charge. Winter temperature is low, gel battery is easy to undercharge, you can properly extend the charging time (such as 10%).
If it is a group of gel battery, when a single gel battery is found to have problems should be replaced in a timely manner, can extend the life of the whole group of gel battery. Thank you for watching, I believe you will be interested in sodium ion battery.