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What is a semi-solid-state battery? A Detailed Introduction
The rapid development of the new energy industry has placed power battery technology in the spotlight. While liquid lithium-ion batteries continue to dominate, the semi-solid-state battery has emerged as a transitional technology, seeking to bridge the gap between liquid and all-solid-state batteries.
However, this pathway is fraught with challenges, as the technology faces competition from both ends of the spectrum. This article explores the technical features, advantages, disadvantages, market applications, and future prospects of the semi-solid-state battery.
What is a semi-solid-state battery?
In the evolution of energy storage technologies, the semi-solid-state battery is gaining traction as a promising solution between liquid lithium-ion and all-solid-state designs. It is defined as a battery in which either one electrode does not contain liquid electrolyte while the other does, or where the solid electrolyte accounts for more than half of the total electrolyte mass or volume.
Working principle of semi-solid batteries
Positive and negative electrode materials: The positive and negative electrode materials of semi-solid batteries follow the common materials in lithium-ion batteries (such as NCM, LFP, etc.), and can also be combined with new materials of solid-state batteries.
Semi-solid electrolyte: It is mainly composed of solid particles and a small amount of liquid electrolyte, which can not only maintain ionic conductivity, but also improve the stability and safety of the battery. It can be a gel-state or polymer-based electrolyte, which has a lower risk of leakage and better high temperature resistance than traditional liquid electrolytes.
Charging and discharging process:
Advantages of the semi-solid-state batteries
High energy density
While conventional lithium-ion batteries are typically capped at 300Wh/kg, the semi-solid-state battery can exceed this limit, achieving 300-400Wh/kg and potentially higher. Some laboratory studies suggest a theoretical energy density of up to 700Wh/kg, nearly twice that of high-performance liquid lithium-ion batteries.
Compact size and lightweight design
Traditional lithium batteries allocate around 40% of their volume and 25% of their weight to the electrolyte (explore the lithium ion battery electrolyte) and separator. By incorporating solid electrolytes, the semi-solid-state battery minimizes these materials, allowing for a more compact design. This makes it ideal for applications requiring strict weight and size constraints, such as drones and electric vehicles.
The feature of flexibility
The use of flexible ceramic-based solid electrolytes enables them to exhibit a certain degree of bending when reduced to millimeter thicknesses. This property is particularly beneficial for wearable devices and flexible electronics.
Enhanced safety
Challenges and barriers faced by semi-solid-state batteries
High production costs
Difficulty in electrolyte content control
Limited industrialization
Although some degree of industrial application has been achieved, the widespread adoption of the semi-solid-state battery still faces technical and market hurdles. The electric vehicle industry, for example, prioritizes cost reduction and efficiency, making it difficult for high-cost technologies to integrate into the supply chain in the short term.
Application scenarios of semi-solid-state batteries
All-Solid-State vs semi-solid-state vs liquid: which is more advantageous?
Future development and breakthroughs
Most current designs use hybrid solid-liquid electrolytes, but their ionic conductivity remains inferior to liquid counterparts. Future innovations must optimize materials like sulfides and oxides to improve battery cycle stability and efficiency.
With increasing production scale, costs are expected to decline. The newly established 6GWh semi-solid-state battery production facility, launched by Guangdong Energy Group and Beijing Weilan New Energy in March 2025, has begun mass production of 314Ah high-capacity cells, setting a precedent for cost reduction.
In the long run, the semi-solid-state battery serves as a stepping stone toward fully solid-state designs. Some companies are actively developing hybrid technologies, such as in-situ solidification methods, to gradually phase out liquid electrolytes.
Conclusion
Although the semi-solid-state battery currently faces challenges related to cost and industrialization, its advantages in safety and energy density make it an attractive choice for electric vehicles, high-end energy storage, drones, and more.
As technology progresses and production scales up, the costs of the semi-solid-state battery are expected to decrease, paving the way for wider adoption. This will contribute to a safer and more efficient energy storage landscape, driving the future of the global new energy industry.
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