{"id":26249,"date":"2023-07-08T09:58:22","date_gmt":"2023-07-08T09:58:22","guid":{"rendered":"https:\/\/batteryswapstation.com\/?p=26249"},"modified":"2023-07-08T09:58:24","modified_gmt":"2023-07-08T09:58:24","slug":"new-battery-solid-electrolyte","status":"publish","type":"post","link":"https:\/\/batteryswapstation.com\/es\/new-battery-solid-electrolyte\/","title":{"rendered":"Nuevo electrolito s\u00f3lido para bater\u00edas que rompe los l\u00edmites de coste-rendimiento"},"content":{"rendered":"<div data-elementor-type=\"wp-post\" data-elementor-id=\"26249\" class=\"elementor elementor-26249\" data-elementor-post-type=\"post\">\n\t\t\t\t<div class=\"elementor-element elementor-element-6286c26 e-flex e-con-boxed e-con e-parent\" data-id=\"6286c26\" data-element_type=\"container\" data-e-type=\"container\">\n\t\t\t\t\t<div class=\"e-con-inner\">\n\t\t\t\t<div class=\"elementor-element elementor-element-cc7b61e elementor-widget elementor-widget-text-editor\" data-id=\"cc7b61e\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<div style=\"line-height: 40px;\">Con el fin de comercializar los productos de estado s\u00f3lido <span style=\"text-decoration: underline;\"><span style=\"color: #333399; text-decoration: underline;\"><a style=\"color: #333399; text-decoration: underline;\" href=\"https:\/\/batteryswapstation.com\/es\/lithium-battery-industry\/\">industria de las pilas de litio<\/a><\/span><\/span>Los electrolitos en estado s\u00f3lido no s\u00f3lo tienen que demostrar un rendimiento excelente, sino tambi\u00e9n una competitividad de costes lo suficientemente fuerte.<\/div><div>\u00a0<\/div><div style=\"line-height: 40px;\">En este sentido, este art\u00edculo presentar\u00e1 un electrolito s\u00f3lido que puede cumplir los requisitos anteriores al mismo tiempo, lo que desempe\u00f1a un papel importante en la promoci\u00f3n de la comercializaci\u00f3n de las bater\u00edas de estado totalmente s\u00f3lido.<\/div>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t<div class=\"elementor-element elementor-element-38a11abb e-flex e-con-boxed e-con e-parent\" data-id=\"38a11abb\" data-element_type=\"container\" data-e-type=\"container\">\n\t\t\t\t\t<div class=\"e-con-inner\">\n\t\t\t\t<div class=\"elementor-element elementor-element-6289ba9a elementor-toc--minimized-on-tablet elementor-widget elementor-widget-table-of-contents\" data-id=\"6289ba9a\" data-element_type=\"widget\" data-e-type=\"widget\" data-settings=\"{&quot;headings_by_tags&quot;:[&quot;h2&quot;,&quot;h3&quot;],&quot;exclude_headings_by_selector&quot;:[],&quot;marker_view&quot;:&quot;numbers&quot;,&quot;no_headings_message&quot;:&quot;No headings were found on this page.&quot;,&quot;minimize_box&quot;:&quot;yes&quot;,&quot;minimized_on&quot;:&quot;tablet&quot;,&quot;hierarchical_view&quot;:&quot;yes&quot;,&quot;min_height&quot;:{&quot;unit&quot;:&quot;px&quot;,&quot;size&quot;:&quot;&quot;,&quot;sizes&quot;:[]},&quot;min_height_tablet&quot;:{&quot;unit&quot;:&quot;px&quot;,&quot;size&quot;:&quot;&quot;,&quot;sizes&quot;:[]},&quot;min_height_mobile&quot;:{&quot;unit&quot;:&quot;px&quot;,&quot;size&quot;:&quot;&quot;,&quot;sizes&quot;:[]}}\" data-widget_type=\"table-of-contents.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<div class=\"elementor-toc__header\">\n\t\t\t\t\t\t<div class=\"elementor-toc__header-title\">\n\t\t\t\t\u00cdndice\t\t\t<\/div>\n\t\t\t\t\t\t\t\t\t\t<div class=\"elementor-toc__toggle-button elementor-toc__toggle-button--expand\" role=\"button\" tabindex=\"0\" aria-controls=\"elementor-toc__6289ba9a\" aria-expanded=\"true\" aria-label=\"Abrir el \u00edndice\"><svg aria-hidden=\"true\" class=\"e-font-icon-svg e-fas-chevron-down\" viewbox=\"0 0 448 512\" xmlns=\"http:\/\/www.w3.org\/2000\/svg\"><path d=\"M207.029 381.476L12.686 187.132c-9.373-9.373-9.373-24.569 0-33.941l22.667-22.667c9.357-9.357 24.522-9.375 33.901-.04L224 284.505l154.745-154.021c9.379-9.335 24.544-9.317 33.901.04l22.667 22.667c9.373 9.373 9.373 24.569 0 33.941L240.971 381.476c-9.373 9.372-24.569 9.372-33.942 0z\"><\/path><\/svg><\/div>\n\t\t\t\t<div class=\"elementor-toc__toggle-button elementor-toc__toggle-button--collapse\" role=\"button\" tabindex=\"0\" aria-controls=\"elementor-toc__6289ba9a\" aria-expanded=\"true\" aria-label=\"Cerrar \u00edndice\"><svg aria-hidden=\"true\" class=\"e-font-icon-svg e-fas-chevron-up\" viewbox=\"0 0 448 512\" xmlns=\"http:\/\/www.w3.org\/2000\/svg\"><path d=\"M240.971 130.524l194.343 194.343c9.373 9.373 9.373 24.569 0 33.941l-22.667 22.667c-9.357 9.357-24.522 9.375-33.901.04L224 227.495 69.255 381.516c-9.379 9.335-24.544 9.317-33.901-.04l-22.667-22.667c-9.373-9.373-9.373-24.569 0-33.941L207.03 130.525c9.372-9.373 24.568-9.373 33.941-.001z\"><\/path><\/svg><\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t<div id=\"elementor-toc__6289ba9a\" class=\"elementor-toc__body\">\n\t\t\t<div class=\"elementor-toc__spinner-container\">\n\t\t\t\t<svg class=\"elementor-toc__spinner eicon-animation-spin e-font-icon-svg e-eicon-loading\" aria-hidden=\"true\" viewbox=\"0 0 1000 1000\" xmlns=\"http:\/\/www.w3.org\/2000\/svg\"><path d=\"M500 975V858C696 858 858 696 858 500S696 142 500 142 142 304 142 500H25C25 237 238 25 500 25S975 237 975 500 763 975 500 975Z\"><\/path><\/svg>\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t<div class=\"elementor-element elementor-element-2dc38341 e-flex e-con-boxed e-con e-parent\" data-id=\"2dc38341\" data-element_type=\"container\" data-e-type=\"container\">\n\t\t\t\t\t<div class=\"e-con-inner\">\n\t\t\t\t<div class=\"elementor-element elementor-element-53c1b074 elementor-widget elementor-widget-text-editor\" data-id=\"53c1b074\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<div style=\"line-height: 40px;\"><iframe loading=\"lazy\" title=\"\u00bfQu\u00e9 son las pilas de litio-metal de estado s\u00f3lido?\" src=\"https:\/\/www.youtube.com\/embed\/azACL3lLMo8\" width=\"1920\" height=\"969\" frameborder=\"0\" allowfullscreen=\"allowfullscreen\"><\/iframe><h2 id=\"characteristics-of-the-current-solid-electrolytes\">Caracter\u00edsticas de los electrolitos s\u00f3lidos actuales<\/h2><p>Desde el punto de vista del rendimiento, en condiciones ideales, los s\u00f3lidos <a href=\"https:\/\/batteryswapstation.com\/es\/lithium-ion-battery-electrolyte\/\"><span style=\"text-decoration: underline; color: #333399;\">electrolito de bater\u00eda de iones de litio<\/span><\/a> necesita tener ventajas en conductividad i\u00f3nica, estabilidad a la oxidaci\u00f3n, estabilidad a la reducci\u00f3n y estabilidad a la humedad al mismo tiempo. Los electrolitos s\u00f3lidos inorg\u00e1nicos descritos pueden dividirse en tres categor\u00edas: \u00f3xidos, sulfuros y haluros.<\/p><p>Como material quebradizo, los \u00f3xidos no pueden cumplir el requisito de deformabilidad. En cambio, tanto los sulfuros como los haluros son capaces de deformarse bajo presiones espec\u00edficas y tambi\u00e9n es relativamente f\u00e1cil conseguir una alta conductividad i\u00f3nica. Sin embargo, el Li2S, la materia prima utilizada para sintetizar sulfuro, es bastante caro, alcanzando $654,18\/kg.<\/p><p>Teniendo en cuenta que la proporci\u00f3n de masa de Li2S en la materia prima del electrolito s\u00f3lido de sulfuro suele ser superior a 30%, el coste de la materia prima no ser\u00e1 inferior a $196,25\/kg. Los haluros s\u00f3lo pueden alcanzar una conductividad i\u00f3nica elevada (&gt; 1 mS cm-1) utilizando tierras raras o cloruro a base de indio y otras materias primas caras para la s\u00edntesis, por lo que el coste de la materia prima tambi\u00e9n es bastante elevado, en la mayor\u00eda de los casos superior a $190\/kg.<\/p><p>Por lo tanto, estos tres tipos de materiales no pueden cumplir los requisitos de conductividad i\u00f3nica, deformabilidad y coste al mismo tiempo. La \u00fanica excepci\u00f3n es el electrolito s\u00f3lido de cloruro de litio y circonio del que inform\u00f3 el grupo de investigaci\u00f3n del profesor Ma Cheng de la Universidad de Ciencia y Tecnolog\u00eda de China en 2021.<\/p><p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-26252\" src=\"https:\/\/batteryswapstation.com\/wp-content\/uploads\/2023\/07\/Characteristics-of-the-current-solid-electrolytes.webp\" alt=\"Caracter\u00edsticas-de-los-electrolitos-s\u00f3lidos-corrientes\" width=\"1000\" height=\"500\" \/><\/p><p>Al no contener elementos de tierras raras ni indio, el coste de la materia prima es inferior a $50\/kg. Sin embargo, la conductividad i\u00f3nica del material es baja, s\u00f3lo unos 0,5 mS cm-1, lo que no puede cumplir los requisitos de eficiencia del transporte de iones.<\/p><p>En general, los electrolitos s\u00f3lidos de \u00f3xido, sulfuro y haluro actuales no son capaces de satisfacer los requisitos de aplicaci\u00f3n en conductividad i\u00f3nica, deformabilidad y competitividad de costes al mismo tiempo.<\/p><p>Sin embargo, muchas de estas propiedades pueden compensarse de otras formas, por ejemplo, aunque la estabilidad de oxidaci\u00f3n o reducci\u00f3n del electrolito s\u00f3lido no sea buena, siempre que el material activo del electrodo se construya sobre el material de revestimiento adecuado, la bater\u00eda podr\u00e1 seguir teniendo un buen rendimiento.<\/p><p>Si se excluyen estas propiedades, el electrolito s\u00f3lido sigue necesitando una buena conductividad i\u00f3nica (superior a 1 mS cm-1 a temperatura ambiente) y deformabilidad (superior a 90% de densidad relativa a 250-350 MPa). Sin embargo, los electrolitos s\u00f3lidos actuales no pueden ofrecer ambas ventajas de rendimiento y, al mismo tiempo, ser suficientemente competitivos en costes (por debajo de $50\/kg).<\/p><h2 id=\"the-new-battery-solid-electrolytes\">Los nuevos electrolitos s\u00f3lidos para pilas<\/h2><p>El grupo de investigaci\u00f3n del profesor Ma Cheng, de la Universidad de Ciencia y Tecnolog\u00eda de China, ha dise\u00f1ado un nuevo electrolito s\u00f3lido de oxicloruro Li1.75ZrCl4.75O0.5, que puede cumplir los requisitos de <span style=\"color: #333399;\"><a style=\"color: #333399;\" href=\"https:\/\/batteryswapstation.com\/es\/solid-state-battery\/\"><span style=\"text-decoration: underline;\">bater\u00eda de estado s\u00f3lido<\/span><\/a><\/span> en los tres aspectos anteriores.<\/p><p>La conductividad i\u00f3nica a temperatura ambiente del Li1.75ZrCl4.75O0.5 alcanza los 2,42 mS cm-1, lo que satisface los requisitos de aplicaci\u00f3n por encima de 1 mS cm-1, y no es inferior a la de los haluros basados en sulfuro y tierras raras\/indium.<\/p><p>Adem\u00e1s, el oxicloruro de litio y circonio tambi\u00e9n presenta una buena deformabilidad, y la densidad relativa tras el prensado en fr\u00edo a 300 MPa alcanza los 94,2%, que supera la de electrolitos s\u00f3lidos conocidos por su buena deformabilidad, como Li3InCl6 y Li10GeP2S12 (la densidad es inferior a 90% a la misma presi\u00f3n).<\/p><p>Debido a las caracter\u00edsticas anteriores, la bater\u00eda de estado totalmente s\u00f3lido compuesta de Li1,75ZrCl4,75O0,5 muestra un rendimiento excelente. La bater\u00eda de estado s\u00f3lido basada en LiNi0,8Mn0,1Co0,1O2 monocristalino puede alcanzar una capacidad de descarga de 70,2 mAh g-1 tras 2082 ciclos con una densidad de corriente de 1000 mA g-1. Este rendimiento es similar al del electrolito s\u00f3lido Li2In1\/3Sc1\/3Cl4, del que se ha informado recientemente en Nature Energy (540 mA g-1, 3000 ciclos, capacidad de descarga final de unos 70 mAh g-1).<\/p><p>Sin embargo, el coste del Li1,75ZrCl4,75O0,5 es muy inferior al del Li2In1\/3Sc1\/3Cl4 ($11,60\/kg frente a $4418,10\/kg, que es menos de 0,3% de este \u00faltimo) y muy por debajo del umbral de $50\/kg mencionado anteriormente. Este material de electrolito s\u00f3lido, muy competitivo en coste y rendimiento, allana el camino para la comercializaci\u00f3n de bater\u00edas totalmente de estado s\u00f3lido.<\/p><h2 id=\"research-process-of-the-new-solid-electrolyte\">Proceso de investigaci\u00f3n del nuevo electrolito s\u00f3lido<\/h2><p>En primer lugar, los investigadores intentaron sintetizar una serie de electrolitos s\u00f3lidos Li2+xZrCl6-xOx mediante el m\u00e9todo de molienda de bolas de alta energ\u00eda. La f\u00f3rmula qu\u00edmica tambi\u00e9n puede expresarse como (1-a)Li2ZrCl6-aLi4ZrCl4O2(a = x\/2). La difracci\u00f3n de rayos X muestra que los componentes con x\u22640,25 presentan una estructura P-3m1. Al seguir aumentando x, aparece en el material una fase con estructura C2\/m que coexiste con la fase P-3m1.<\/p><figure id=\"attachment_26253\" aria-describedby=\"caption-attachment-26253\" style=\"width: 1000px\" class=\"wp-caption alignnone\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-26253\" src=\"https:\/\/batteryswapstation.com\/wp-content\/uploads\/2023\/07\/composition-dependent-phase-evolution-in-Li2xZrCl6-xOx.webp\" alt=\"evoluci\u00f3n de fase dependiente de la composici\u00f3n en-Li2+xZrCl6-xOx\" width=\"1000\" height=\"673\" \/><figcaption id=\"caption-attachment-26253\" class=\"wp-caption-text\">Evoluci\u00f3n de fase dependiente de la composici\u00f3n en Li2+xZrCl6-xOx<\/figcaption><\/figure><p>Cuando x\u22651,0, el material presenta \u00fanicamente la fase C2\/m. En la regi\u00f3n de coexistencia de dos fases entre 0,25&lt;x&lt;1,0, la estructura cristalina del material es especialmente vulnerable a los da\u00f1os causados por la molienda de bolas de alta energ\u00eda, y la cristalinidad es inferior a 20%. Dado que los electrolitos s\u00f3lidos de cloruro basados en Zr suelen depender de fases amorfas para el transporte eficiente de iones, esto podr\u00eda significar que los materiales con coexistencia 0,25&lt;x&lt;1,0 de estas fases cristalinas dobles tienen una conductividad i\u00f3nica m\u00e1s alta.<\/p><p>El ensayo de espectroscopia de impedancia electroqu\u00edmica (EIS) muestra que los componentes con coexistencia de doble fase cristalina presentan una conductividad i\u00f3nica m\u00e1s elevada. De acuerdo con los resultados esperados, la conductividad i\u00f3nica a temperatura ambiente de los componentes bif\u00e1sicos con menor cristalinidad es generalmente superior a la de los componentes monof\u00e1sicos.<\/p><p>En el punto de componente x=0,5 (f\u00f3rmula qu\u00edmica:Li2,5ZrCl5,5O0,5), la conductividad i\u00f3nica a temperatura ambiente alcanza 1,17 mS cm-1, lo que no est\u00e1 mal incluso si se compara con los electrolitos s\u00f3lidos de tierras raras o haluros basados en indio.<\/p><figure id=\"attachment_26254\" aria-describedby=\"caption-attachment-26254\" style=\"width: 1000px\" class=\"wp-caption alignnone\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-26254\" src=\"https:\/\/batteryswapstation.com\/wp-content\/uploads\/2023\/07\/li-ion-transport-behavior-of-Li2xZrCl6-xOx.webp\" alt=\"li-ion-transport-behavior-of-Li2+xZrCl6-xOx\" width=\"1000\" height=\"406\" \/><figcaption id=\"caption-attachment-26254\" class=\"wp-caption-text\">Comportamiento del transporte de iones Li2+xZrCl6-xOx<\/figcaption><\/figure><p>Aunque la conductividad i\u00f3nica de los materiales mencionados ha superado 1 mS cm-1, a\u00fan puede mejorarse. Seg\u00fan la tendencia de la conductividad i\u00f3nica con la composici\u00f3n, los investigadores descubrieron que cuando la composici\u00f3n de la regi\u00f3n bif\u00e1sica en el diagrama de fases est\u00e1 cerca de su l\u00edmite de fase con la regi\u00f3n monof\u00e1sica, la conductividad i\u00f3nica mejorar\u00e1.<\/p><p>Para controlar con precisi\u00f3n la composici\u00f3n y acercarla al l\u00edmite de fase, los investigadores introdujeron un tercer componente LiZrCl5 sobre la base del componente anterior Li2.5ZrCl5.5O0.5 (es decir, 75%Li2ZrCl6-25%Li4ZrCl4O2) con la conductividad i\u00f3nica m\u00e1s elevada.<\/p><p>Esto da lugar a una serie de componentes (75%-y)Li2ZrCl6-25%Li4ZrCl4O2-yLiZrCl5 o Li2,5-yZrCl5,5-yO0,5. Seg\u00fan los resultados de difracci\u00f3n de rayos X, con el aumento de y, la intensidad del pico de difracci\u00f3n de la fase P-3m1 en Li2.5-yZrCl5.5-yO0.5\uff08y\u22640.75\uff09 aumenta gradualmente, mientras que la de la fase C2\/m disminuye gradualmente.<\/p><p>Cuando y=0,75, aunque la fase P-3m1 y la fase C2\/m siguen coexistiendo, el pico caracter\u00edstico de esta \u00faltima se vuelve extremadamente d\u00e9bil, lo que indica que el componente est\u00e1 bastante cerca del l\u00edmite de fase entre la regi\u00f3n bif\u00e1sica y la regi\u00f3n monof\u00e1sica en el diagrama de fases.<\/p><p>Como era de esperar, la conductividad i\u00f3nica a temperatura ambiente del Li2,5-yZrCl5,5-yO0,5 aumenta significativamente con el incremento de y (es decir, la composici\u00f3n contin\u00faa acerc\u00e1ndose al l\u00edmite de fase entre la regi\u00f3n monof\u00e1sica y la regi\u00f3n bif\u00e1sica en el diagrama de fases).<\/p><p>Para la regi\u00f3n bif\u00e1sica de composici\u00f3n y=0,75 (f\u00f3rmula qu\u00edmica: Li1,75ZrCl4,75O0,5), la conductividad i\u00f3nica del material a 25\u00b0C alcanza 2,42 mS cm-1, superando a electrolitos s\u00f3lidos como Li3InCl6 y Li2In1\/3Sc1\/3Cl4, que se basan en materias primas caras.<\/p><figure id=\"attachment_26255\" aria-describedby=\"caption-attachment-26255\" style=\"width: 1000px\" class=\"wp-caption alignnone\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-26255\" src=\"https:\/\/batteryswapstation.com\/wp-content\/uploads\/2023\/07\/structure-and-ionic-conductivities-of-Li2.5-yZrCl5.5-yO0.5.webp\" alt=\"estructura-y-conductividades-i\u00f3nicas-de-Li2.5-yZrCl5.5-yO0.5\" width=\"1000\" height=\"670\" \/><figcaption id=\"caption-attachment-26255\" class=\"wp-caption-text\">Estructuras y conductividades i\u00f3nicas de Li2.5-yZrCl5.5-yO0.5<\/figcaption><\/figure><p>Adem\u00e1s de la conductividad i\u00f3nica, la deformabilidad del Li1,75ZrCl4,75O0,5 tambi\u00e9n es bastante excelente. Esta propiedad puede evaluarse por la densidad relativa que el material puede alcanzar a determinadas presiones. Cuanto mejor sea la deformabilidad, mayor ser\u00e1 la densidad relativa que puede alcanzar el material a una presi\u00f3n determinada.<\/p><p>Las pruebas experimentales muestran que la densidad relativa de electrolitos s\u00f3lidos inorg\u00e1nicos como Li6PS5Cl, Li10GeP2S12, Li3InCl6 y Li2ZrCl6, conocidos por su buena deformabilidad, es inferior a 90% a 300 MPa. En cambio, Li1.75ZrCl4.75O0.5 tiene una densidad relativa de 94,2% a 300 MPa, por lo que su deformabilidad supera a la de todos los electrolitos s\u00f3lidos mencionados anteriormente.<\/p><figure id=\"attachment_26256\" aria-describedby=\"caption-attachment-26256\" style=\"width: 1000px\" class=\"wp-caption alignnone\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-26256\" src=\"https:\/\/batteryswapstation.com\/wp-content\/uploads\/2023\/07\/Compressibility-of-LZCO.webp\" alt=\"Compresibilidad de LZCO\" width=\"1000\" height=\"644\" \/><figcaption id=\"caption-attachment-26256\" class=\"wp-caption-text\">Compresibilidad de LZCO<\/figcaption><\/figure><p>La excelente conductividad i\u00f3nica y la buena deformabilidad permiten que las bater\u00edas de estado s\u00f3lido compuestas por electrolitos de estado s\u00f3lido Li1.75ZrCl4.75O0.5 demuestren un excelente rendimiento.<\/p><p>Una bater\u00eda de estado totalmente s\u00f3lido que utiliza LiCoO2 (LCO) sin recubrimiento como electrodo positivo, aleaci\u00f3n de Li-In como <span style=\"color: #333399;\"><a style=\"color: #333399;\" href=\"https:\/\/batteryswapstation.com\/es\/lithium-ion-battery-anode-materials\/\"><span style=\"text-decoration: underline;\">\u00e1nodo de bater\u00eda de iones de litio<\/span><\/a><\/span>Li1.75ZrCl4.75O0.5 como electrolito s\u00f3lido, y Li6PS5Cl como capa tamp\u00f3n entre Li1.75ZrCl4.75O0.5 y el electrodo negativo, la eficiencia coulombiana de primer ciclo de hasta 98,28% a 25 \u00b0C, 14 mA g-1. Es mejor que el mismo tipo de bater\u00eda de estado s\u00f3lido descrito en la bibliograf\u00eda.<\/p><p>Adem\u00e1s, tras 150 ciclos de la bater\u00eda de estado s\u00f3lido basada en LCO a una alta densidad de corriente de 25 \u00b0C y 700 mA g-1, la capacidad b\u00e1sicamente no se aten\u00faa, y a\u00fan puede alcanzarse la capacidad de descarga de 102 mAh g-1. Una bater\u00eda similar compuesta de Li2ZrCl6 tiene una capacidad de descarga similar (114 mAh g-1) despu\u00e9s de 100 ciclos a una densidad de corriente de s\u00f3lo 1\/10 de los valores anteriores ( 70 mA g-1).<\/p><figure id=\"attachment_26257\" aria-describedby=\"caption-attachment-26257\" style=\"width: 1000px\" class=\"wp-caption alignnone\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-26257\" src=\"https:\/\/batteryswapstation.com\/wp-content\/uploads\/2023\/07\/Electrochemical-performance-of-the-Li-InLPSCH-LZCOLCO-cell.webp\" alt=\"Rendimiento electroqu\u00edmico de la c\u00e9lula Li-In,LPSCH-LZCO,LCO\" width=\"1000\" height=\"579\" \/><figcaption id=\"caption-attachment-26257\" class=\"wp-caption-text\">Rendimiento electroqu\u00edmico de la c\u00e9lula Li-In,LPSCH-LZCO,LCO<\/figcaption><\/figure><p>Cuando se utiliza el cristal \u00fanico LiNi0.8Mn0.1Co0.1O2\uff08scNMC811\uff09 como el <span style=\"text-decoration: underline;\"><span style=\"color: #333399; text-decoration: underline;\"><a style=\"color: #333399; text-decoration: underline;\" href=\"https:\/\/batteryswapstation.com\/es\/cathode-materials\/\">materiales cat\u00f3dicos<\/a><\/span><\/span>Sin embargo, la bater\u00eda de estado s\u00f3lido sigue mostrando un excelente rendimiento c\u00edclico. La eficiencia coulombiana del primer ciclo de la bater\u00eda a 25 \u00b0C y 20 mA g-1 es de 87,31%.<\/p><p>Incluso despu\u00e9s de 2.082 ciclos a una densidad de corriente elevada de 1.000 mA g-1, la capacidad de descarga a\u00fan puede alcanzar los 70,2 mAh g-1. Recientemente se ha publicado en Nature Energy una bater\u00eda de rendimiento similar (540 mA g-1, 3000 ciclos, capacidad de descarga final de unos 70 mAh g-1) con electrolito s\u00f3lido Li2In1\/3Sc1\/3Cl4.<\/p><p>Sin embargo, como la s\u00edntesis de Li1,75ZrCl4,75O0,5 no requiere el uso de compuestos caros como el cloruro de tierras raras y el sulfuro de litio, su coste de materia prima es de s\u00f3lo $11,60\/kg, menos de 0,3% del coste de materia prima de Li2In1\/3Sc1\/3Cl4 ($4418,10\/kg). Tambi\u00e9n est\u00e1 muy por debajo del umbral de $50\/kg mencionado anteriormente. Por lo tanto, el Li1.75ZrCl4.75O0.5 es muy competitivo tanto en coste como en rendimiento.<\/p><figure id=\"attachment_26258\" aria-describedby=\"caption-attachment-26258\" style=\"width: 1000px\" class=\"wp-caption alignnone\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-26258\" src=\"https:\/\/batteryswapstation.com\/wp-content\/uploads\/2023\/07\/Electrochemical-performance-of-the-Li-InLPSCH-LZCOscNMCSII-cell.webp\" alt=\"Rendimiento electroqu\u00edmico de la c\u00e9lula Li-In,LPSCH-LZCO,scNMCSII\" width=\"1000\" height=\"567\" \/><figcaption id=\"caption-attachment-26258\" class=\"wp-caption-text\">Rendimiento electroqu\u00edmico de la c\u00e9lula Li-In,LPSCH-LZCO, scNMCSII<\/figcaption><\/figure><h2 id=\"summary-and-prospect\">Resumen y perspectivas<\/h2><p>El grupo de investigaci\u00f3n del profesor Ma Cheng dise\u00f1\u00f3 y sintetiz\u00f3 un nuevo tipo de electrolito s\u00f3lido policristalino de cloruro de \u00f3xido Li1.75ZrCl4.75O0.5. En t\u00e9rminos de rendimiento, el material tiene m\u00e1s conductividad i\u00f3nica que Li3InCl6, Li2In1\/3Sc1\/3Cl4 y otros electrolitos s\u00f3lidos de alto rendimiento, y es mejor que los electrolitos s\u00f3lidos f\u00e1cilmente deformables como Li6PS5Cl y Li10GeP2S12.<\/p><p>La capacidad de descarga de una bater\u00eda de estado s\u00f3lido compuesta por este material tras 2082 ciclos a una alta densidad de corriente de 1000 mA g-1 se aproxima a la de una bater\u00eda similar basada en Li2In1\/3Sc1\/3Cl4 tras 3000 ciclos a 540 mA g-1.<\/p><p>En cuanto al coste, como el Li1,75ZrCl4,75O0,5 puede sintetizarse a partir de compuestos baratos como LiOH-H2O, LiCl, ZrCl4, su coste como materia prima es de s\u00f3lo $11,60\/kg, que no s\u00f3lo es inferior al de otros electrolitos s\u00f3lidos con propiedades similares (en su mayor\u00eda en torno a $200\/kg o m\u00e1s). Tambi\u00e9n es inferior al umbral de $50\/kg necesario para su comercializaci\u00f3n.<\/p><p>Adem\u00e1s, si se sintetiza a partir del m\u00e1s barato ZrOCl2-8H2O, LiCl y ZrCl4, el coste del Li1.75ZrCl4.75O0.5 puede reducirse a\u00fan m\u00e1s sobre la base de $11,60\/kg. El descubrimiento del Li1,75ZrCl4,75O0,5 rompi\u00f3 el l\u00edmite del \"coste-rendimiento\" que puede alcanzar el electrolito s\u00f3lido. Este electrolito s\u00f3lido de bajo coste y alto rendimiento dar\u00e1 un gran impulso a la comercializaci\u00f3n de las bater\u00edas totalmente s\u00f3lidas.<\/p><\/div>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t<div class=\"elementor-element elementor-element-71fa1340 e-flex e-con-boxed e-con e-parent\" data-id=\"71fa1340\" data-element_type=\"container\" data-e-type=\"container\">\n\t\t\t\t\t<div class=\"e-con-inner\">\n\t\t\t\t<div class=\"elementor-element elementor-element-31177567 elementor-widget elementor-widget-heading\" data-id=\"31177567\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"heading.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t<div class=\"elementor-heading-title elementor-size-default\">Puestos relacionados<\/div>\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t<div class=\"elementor-element elementor-element-290c50a4 e-flex e-con-boxed e-con 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class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t<div class=\"elementor-posts-container elementor-posts elementor-posts--skin-classic elementor-grid\" role=\"list\">\n\t\t\t\t<article class=\"elementor-post elementor-grid-item post-25911 post type-post status-publish format-standard has-post-thumbnail hentry category-battery-industry category-battery-knowledge category-different-battery-technology tag-battery tag-lithium tag-power\" role=\"listitem\">\n\t\t\t\t<a class=\"elementor-post__thumbnail__link\" href=\"https:\/\/batteryswapstation.com\/es\/gel-motorcycle-battery\/\" tabindex=\"-1\" >\n\t\t\t<div class=\"elementor-post__thumbnail\"><img loading=\"lazy\" decoding=\"async\" width=\"300\" height=\"225\" src=\"https:\/\/batteryswapstation.com\/wp-content\/uploads\/2023\/06\/Gel-motorcycle-battery-features-and-differences-300x225.webp\" class=\"attachment-medium size-medium wp-image-25914\" alt=\"Caracter\u00edsticas y diferencias de las bater\u00edas de gel para motocicletas\" 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class=\"elementor-post__meta-data\">\n\t\t\t\t\t<span class=\"elementor-post-date\">\n\t\t\t13 de diciembre de 2022\t\t<\/span>\n\t\t\t\t<span class=\"elementor-post-avatar\">\n\t\t\tNo hay comentarios\t\t<\/span>\n\t\t\t\t<\/div>\n\t\t\n\t\t<a class=\"elementor-post__read-more\" href=\"https:\/\/batteryswapstation.com\/es\/electrolysis-tank-manufacturers\/\" aria-label=\"Read more about Top 5 electrolysis tank manufacturers in China\" tabindex=\"-1\" >\n\t\t\tLeer M\u00e1s \"\t\t<\/a>\n\n\t\t\t\t<\/div>\n\t\t\t\t<\/article>\n\t\t\t\t<\/div>\n\t\t\n\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>","protected":false},"excerpt":{"rendered":"<p>Este art\u00edculo presenta el nuevo electrolito s\u00f3lido para bater\u00edas, su proceso de investigaci\u00f3n y la comparaci\u00f3n con los electrolitos s\u00f3lidos actuales.<\/p>","protected":false},"author":20,"featured_media":26250,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_lmt_disableupdate":"","_lmt_disable":"","_rtcl_gb_attr":"","footnotes":""},"categories":[224,223,222],"tags":[220,228,221],"class_list":["post-26249","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-battery-industry","category-battery-materials","category-battery-news","tag-battery","tag-cell","tag-lithium"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.1.1 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>New battery solid electrolyte breaking the cost performance limits - TYCORUN<\/title>\n<meta name=\"description\" content=\"This article introduces the new battery solid electrolyte, about its research process and the comparison with the current solid electrolytes.\" \/>\n<meta name=\"robots\" content=\"index, follow, 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